Title of article
Electrocatalytic reduction of carbon dioxide by a polymeric film of rhenium tricarbonyl dipyridylamine
Author/Authors
Kwong-Chak Cheung، نويسنده , , Peng Guo، نويسنده , , Ming-Him So، نويسنده , , Lawrence Yoon Suk Lee، نويسنده , , Kam-Piu Ho، نويسنده , , Wing-Leung Wong، نويسنده , , Kam-Han Lee، نويسنده , , Wing-Tak Wong، نويسنده , , Zhong-Yuan Zhou، نويسنده , , Kwok-Yin Wong، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
4
From page
2842
To page
2845
Abstract
A dipyridylamine ligand with a pendant pyrrole (N-(3-N,N′-bis(2-pyridyl)propylamino)pyrrole, PPP) and its corresponding rhenium(I) complex, Re(CO)3(κ2-N,N-PPP)Cl, were synthesized. The structure of Re(CO)3(κ2-N,N-PPP)Cl was determined by X-ray crystallography. Electrochemical polymerization of the pyrrole moiety resulted in the immobilization of poly[Re(CO)3(κ2-N,N-PPP)Cl] film onto a glassy carbon electrode, which exhibited electrocatalytic activity for the reduction of CO2 to CO.
Keywords
Rhenium complex , Polypyrrole films , Carbon dioxide , Electrocatalysis
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1374623
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