Title of article
The use of a new carboranylamidophosphite ligand in the asymmetric Pd-catalysed allylic alkylation in organic solvents and supercritical carbon dioxide
Author/Authors
Sergey E. Lyubimov، نويسنده , , Ilya V. Kuchurov، نويسنده , , Andrei A. Vasil’ev، نويسنده , , Andrey A. Tyutyunov، نويسنده , , Valery N. Kalinin، نويسنده , , Vadim A. Davankov، نويسنده , , Sergei G. Zlotin، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
3
From page
3047
To page
3049
Abstract
A novel P-monodentate ligand based on carboranyl alcohol and (S)-2-(anilinomethyl)pyrrolidine provides high enantioselectivities (ee’s up to 95%) in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenylallyl acetate. The first example of the Pd-catalysed allylic alkylation in supercritical carbon dioxide is also described.
Keywords
Carboranyldiamidophosphite , Palladium , Asymmetric allylic alkylation , Supercritical carbon dioxide
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1374685
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