Title of article
Pyrolysis of poly[2,4,6-tri(methylamino)borazine] and its conversion into BN fibers
Author/Authors
S Bernard، نويسنده , , D Cornu، نويسنده , , P Miele، نويسنده , , H Vincent، نويسنده , , J Bouix، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
7
From page
91
To page
97
Abstract
The pyrolysis process of poly[2,4,6-tri(methylamino)borazine]-based fibers has been studied in detail. The condensation of polymer leads to infusible fibers with a three-dimensional polymeric network from 70 to 400 °C. A polymer–mineral transition occurs since 400 to give amorphous hydrogenated fibers at 1000 °C. The chemical conversion process is complete at 1400 °C and the BN fibers crystallize up to 1800 °C.
Keywords
PolyMAB , cross-link , Polymer–mineral transition , BN fibers , Crystallization , Ceramization
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1374688
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