Title of article
Polyhedral monocarbaborane chemistry: The C,B-para-diphenyl monocarbadodecaborane anion [1,12-Ph2-closo-1-CB11H10]−
Author/Authors
Andreas Franken، نويسنده , , Colin A. Kilner، نويسنده , , Mark Thornton-Pett، نويسنده , , John D Kennedy، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
4
From page
176
To page
179
Abstract
Iodination of Cs+[1-Ph-closo-1-CB11H11]− with I2 in CH3COOH solution gives Cs+[1-Ph-closo-1-CB11H10-12-I]− (78%); reaction of Cs+[1-Ph-closo-1-CB11H10-12-I]− with PhMgBr and [PdCl2(PPh3)2] in THF solution thence gives the [1,12-Ph2-closo-1-CB11H10]− anion (49% as its Cs+ salt), characterised by NMR spectroscopy and a single-crystal X-ray diffraction analysis of its [NEt4]+ salt.
Keywords
B-substitution , Closed monocarbaborane , B-phenylation , B-diphenylation , X-Ray structures , C
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1374712
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