Title of article
Structural characterization and catalytic activity of the rhodium–carbene complex Rh(PPh3)2(IMes)Cl (IMes=bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)
Author/Authors
Gabriela A. Grasa، نويسنده , , Zakhia Moore، نويسنده , , Kenneth L. Martin، نويسنده , , Edwin D. Stevens، نويسنده , , Steven P. Nolan، نويسنده , , Valérie Paquet، نويسنده , , Hélène Lebel، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2002
Pages
6
From page
126
To page
131
Abstract
The rhodium–carbene complex Rh(PPh3)2(IMes)Cl (2) is an active catalyst for the hydroboration of simple olefins at room temperature. The reactivity of 2 was also tested in the methylenation of aldehydes. The crystal structure of 2 is also reported.
Keywords
Structural characterization , Catalytic activity , Rhodium–carbene complexes
Journal title
Journal of Organometallic Chemistry
Serial Year
2002
Journal title
Journal of Organometallic Chemistry
Record number
1374784
Link To Document