• Title of article

    Addition of organolithium compounds to tricarbonyl(tropone)iron complexes: experimental and structural studies

  • Author/Authors

    Yoann Coquerel، نويسنده , , Jean-Pierre Deprés، نويسنده , , Andrew E Greene، نويسنده , , Christian Philouze، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2002
  • Pages
    10
  • From page
    176
  • To page
    185
  • Abstract
    The regioselectivity (1,2 vs. 1,4) in the nucleophilic addition of organolithium reagents to tropone(tricarbonyl)iron complexes has been studied and found to be correlated with the relative hardness of the nucleophile (HSAB principle). X-ray structures of several 1,2 and 1,4 adducts are reported.
  • Keywords
    Tricarbonyl(tropone)iron complexes , Nucleophilic addition
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2002
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1374868