• Title of article

    Cyclic thioether and acyclic thioether–thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)

  • Author/Authors

    Lai Yoong Goh، نويسنده , , Ming Ern Teo، نويسنده , , Soo Beng Khoo، نويسنده , , Weng Kee Leong، نويسنده , , Jagadese J Vittal، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2002
  • Pages
    9
  • From page
    161
  • To page
    169
  • Abstract
    The reaction of [Cp*RuCl2]2 (7) (Cp*=η5-C5Me5) with S(CH2CH2S−)2 (tpdt) and trithiacyclononane (9S3) gave the monomeric complexes Cp*Ru(tpdt) (6) and [Cp*Ru(9S3)](PF6) (8) as dark purple and yellow crystals, respectively. Treatment of 6 with 7 and [(C6Me6)RuCl2]2 (2) led to the isolation of RuRu bonded complexes [Cp*Ru(tpdt)(Ru(Cl)Cp*](PF6) (9) and [Cp*Ru(tpdt)(Ru(C6Me6)](PF6) (10) as dark red and purple crystals, respectively. The complexes, 6 and 8–10 have been spectrally and structurally characterized.
  • Keywords
    Structures , Pentamethylcyclopentadienyl , Thiolate–thioether , 5-dithiolate , 3-Thiapentane-1 , Ruthenium
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2002
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1375124

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1375124