Title of article
Palladium-catalyzed asymmetric allylic substitution using planar chiral hydrazone ligands
Author/Authors
Takashi Mino، نويسنده , , Teruhiro Ogawa، نويسنده , , Masakazu Yamashita، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
5
From page
122
To page
126
Abstract
Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate (3) with a dimethyl malonate–BSA–LiOAc system has been successfully carried out in the presence of planar chiral phosphine-hydrazone ligands such as 2a in good yields with good enantioselectivities (up to 96% ee).
Keywords
Palladium , Hydrazone , Ferrocene , Asymmetric catalysis , Allylic Alkylation , Allylic amination
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1375220
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