Title of article
Catalysis of triethoxysilane disproportionation with oligoethylene glycol ethers
Author/Authors
Lidiya N. Parshina، نويسنده , , Lyudmila A. Oparina، نويسنده , , Marina Ya. Khilʹko، نويسنده , , Boris A. Trofimov، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
4
From page
246
To page
249
Abstract
Oligoethylene glycol ethers catalyze the disproportionation of triethoxysilane to tetraethoxysilane and silane both at room temperature and upon heating. For comparison, the CsF-catalyzed disproportionation of triethoxysilane has been examined and found more facile. Mechanisms of the reactions involving formation of hypervalent silicon complexes have been discussed.
Keywords
Tetraethoxysilane , Triethoxysilane , Silane , Oligoethylene glycol ethers , Hypervalent silicon complexes , Disproportionation
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1375253
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