Title of article
Chiral carborane-derived thiophosphites: A new generation of ligands for Rh-catalyzed asymmetric hydrogenation
Author/Authors
Sergey E. Lyubimov، نويسنده , , Vadim A. Davankov، نويسنده , , Pavel V. Petrovskii، نويسنده , , Evamarie Hey-Hawkins، نويسنده , , Andrey A. Tyutyunov، نويسنده , , Evgeny G. Rys، نويسنده , , Valery N. Kalinin، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
3
From page
3689
To page
3691
Abstract
A new class of chiral monodentate ligands – carborane-containing thiophosphites have been synthesized and tested in the Rh-catalyzed asymmetric hydrogenation of prochiral olefins with the result of up to 99% ee. The dependence of the enantioselectivity on the electronic properties of the carboranyl substituent has been studied.
Keywords
Thiophosphite ligands , asymmetric hydrogenation , Carboranes , Rhodium
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1375437
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