Title of article
Gold(I)-catalyzed synthesis of (1E,3E)-dienes from propargylic esters
Author/Authors
Alexander S. Dudnik، نويسنده , , Todd Schwier، نويسنده , , Vladimir Gevorgyan، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2009
Pages
4
From page
482
To page
485
Abstract
A mild and stereoselective gold(I)-catalyzed domino transformation of propargylic esters leading to substituted (1E,3E)-dienes has been developed. This cascade process proceeds via a sequence of 1,3-acyloxy- or 1,3-phosphatyloxy migrations to form allenic intermediate followed by a proton transfer.
Keywords
propargylic esters , 1 , 3-dienes , Gold , Homogeneous catalysis , rearrangement
Journal title
Journal of Organometallic Chemistry
Serial Year
2009
Journal title
Journal of Organometallic Chemistry
Record number
1375640
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