Title of article
Novel sandwich complexes of zirconium [C9H5(SiMe3)2](C5Me4R)ZrCl2 (R = CH3, CH2CH2NMe2): Synthesis and reduction behavior
Author/Authors
Sergey A. Belov، نويسنده , , Roman S. Kirsanov، نويسنده , , Dmitrii P. Krut’ko، نويسنده , , Dmitrii A. Lemenovskii، نويسنده , , Andrei V. Churakov، نويسنده , , Judith A.K. Howard، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
7
From page
1912
To page
1918
Abstract
Novel half-sandwich [C9H5(SiMe3)2]ZrCl3 (3) and sandwich [C9H5(SiMe3)2](C5Me4R)ZrCl2 (R = CH3 (1), CH2CH2NMe2 (2)) complexes were prepared and characterized. The reduction of 2 by Mg in THF lead to (η5-C9H5(SiMe3)2)[η5:η2(C,N)-C5Me4CH2CH2N(Me)CH2]ZrH (7). The structure of 7 was proved by NMR spectroscopy data. Hydrolysis of 2 resulted in the binuclear complex ([C5Me4CH2CH2NMe2]ZrCl2)2O (6). The crystal structures of 1 and 6 were established by X-ray diffraction analysis.
Keywords
Zirconium , Cyclopentadienyl ligands , Indenyl ligands , Oxidative addition , Reduction , N ligands
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1375816
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