Title of article
Indium-catalyzed Barbier allylation reaction
Author/Authors
Jacques Augé، نويسنده , , Nadège Lubin-Germain، نويسنده , , Sylvain Marque، نويسنده , , Latifa Seghrouchni، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
5
From page
79
To page
83
Abstract
Barbier allylation reaction of carbonyl compounds with allyl bromide was investigated using a catalytic amount of indium (0), indium (I) or indium (III) salts in the presence of a reducer and chlorotrimethylsilane (TMSCl). The Mn/TMSCl couple turned out to be the most efficient system to regenerate active indium in the allylation reaction of various carbonyl compounds including α- and β-oxygenated aldehydes.
Keywords
Homocoupling , manganese , Indium , Catalysis , Allylation reaction
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1375864
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