Title of article
Synthesis and structural characterization of an 11-vertex nido-diphosphaborane, 7,9-Ph2-nido-7,9-P2B9H9
Author/Authors
Daewon Hong، نويسنده , , Patrick J. Carroll and Mohan Rao Kollipara، نويسنده , , Larry G. Sneddon، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
5
From page
61
To page
65
Abstract
The new 11-vertex nido-diphosphaborane, 7,9-Ph2-nido-7,9-P2B9H9, has been synthesized by the reaction of Me4N+[nido-B9H12−] with PhPCl2 in the presence of NaH. A single crystal X-ray diffraction determination and DFT/GIAO/NMR methods have both established that the compound has an open cage structure containing the phosphorus atoms in non-adjacent positions on the open face.
Keywords
Heteroborane , Boron , DFT/GIAO , Diphosphaborane
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1375911
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