Title of article
A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII)–Cis-and trans-coordination of the ligand
Author/Authors
Mingdong Zhou، نويسنده , , Shuliang Zang، نويسنده , , Eberhardt Herdtweck، نويسنده , , Fritz E. Kühn، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
5
From page
2473
To page
2477
Abstract
A (salicylidene)aniline derived Schiff-base adduct of methyltrioxorhenium(VII), displaying both a cis- and a trans-arrangement of the Schiff-base ligand to the Re bound methyl group has been synthesized and described. Despite displaying some significant differences in the solid state (e.g. Re–O (Schiff base) bond distance, Re–C bond distance and several bond angles), the two configurations are indistinguishable in solution, obviously interchanging quickly.
Keywords
Catalysis , Methyltrioxorhenium(VII) , solid state structure , Schiff base , Salicylidene(aniline)
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1375958
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