Title of article
Synthesis, structure and some reactions of (C5Me4hex)2Ru2(CO)4
Author/Authors
Siyabonga Ngubane، نويسنده , , Mikael Hakansson، نويسنده , , Susan Jagner، نويسنده , , John R. Moss، نويسنده , , Akella Sivaramakrishna، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2008
Pages
6
From page
343
To page
348
Abstract
The synthesis of the new cyclopentadiene, C5Me4(hex)H is described and its reaction with Ru3(CO)12 to yield (C5Me4hex)2Ru2(CO)4 (hex = n-hexyl) is reported. The X-ray crystal structure of the dimer confirms the structure with bridging and terminal CO groups. Reactions of the dimer to yield (C5Me4hex)Ru(CO)2X (X = Cl, Br, I) are reported. IR, NMR and mass spectra are reported for all new compounds. The solubility of the dimer is found to be 10 times greater than that for (C5Me5)2Ru2(CO)4.
Keywords
structure , Ruthenium , Cyclopentadienyl , Carbonyl , dimer
Journal title
Journal of Organometallic Chemistry
Serial Year
2008
Journal title
Journal of Organometallic Chemistry
Record number
1376232
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