Title of article
Enantioselective catalysis: Part 147. A Rh(cod) complex with the chiral [Pt2S2{(−)diop}2] ligand
Author/Authors
Henri Brunner، نويسنده , , Matthias Weber، نويسنده , , Manfred Zabel، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2003
Pages
7
From page
6
To page
12
Abstract
The trinuclear complex [Pt2Rh(μ3-S)2{(−)-diop}2(cod)]Cl (3) was synthesized starting from the chiral “ligand” [Pt2(μ-S)2{(−)-diop}] (2) and [Rh(cod)Cl]2, and characterized by X-ray crystallography. Compound 3 was used as a catalyst in the hydrosilylation of acetophenone with diphenylsilane and in the hydrogenation of ketopantolactone.
Keywords
Platinum , Rhodium , enantioselective catalysis , Heterometallic complexes
Journal title
Journal of Organometallic Chemistry
Serial Year
2003
Journal title
Journal of Organometallic Chemistry
Record number
1376273
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