• Title of article

    Palladium-catalyzed reaction of aryl iodides with tertiary propargylic amides.: Highly substituted allenes through a regioselective carbopalladation/β-NPd elimination reaction

  • Author/Authors

    Antonio Arcadi، نويسنده , , Sandro Cacchi، نويسنده , , Giancarlo Fabrizi، نويسنده , , Fabio Marinelli، نويسنده , , Luca M Parisi، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2003
  • Pages
    5
  • From page
    562
  • To page
    566
  • Abstract
    The palladium-catalyzed reaction of aryl iodides with tertiary propargylic amides affords highly substituted allenes. Best results have been obtained by using Pd(OAc)2, nBu3N, HCOOH, and nBu4NCl or LiCl in DME at 100 °C. The reaction is highly regioselective and the carbopalladation step is controlled by the strong directing effect of the tertiary amide group.
  • Keywords
    Palladium , Allenes , hydroarylation , alkynes
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2003
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1376563

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1376563