Title of article
An alkylzinc bromide and a lithium alkyldibromozincate containing tris(organosilyl)methyl groups
Author/Authors
Davood Azarifar، نويسنده , , Martyn P. Coles، نويسنده , , Salima M. El-Hamruni، نويسنده , , Colin Eaborn، نويسنده , , Peter B. Hitchcock، نويسنده , , J.David Smith، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2004
Pages
5
From page
1718
To page
1722
Abstract
The lithium reagent (3) reacts with a molar equivalent of anhydrous zinc bromide to give the dimeric compound (2a), in which zinc is four-coordinate. The product from a similar reaction with Li{C(SiMe3)2(SiMe2NPhMe)} is the lithium zincate [Li(THF)2(μ-Br)2Zn{C(SiMe3)2(SiMe2NPhMe)}] (4), in which the zinc is only three-coordinate. The crystal structures of 2a and 4 have been determined.
Keywords
crystal structures , Organozinc , organosilyl
Journal title
Journal of Organometallic Chemistry
Serial Year
2004
Journal title
Journal of Organometallic Chemistry
Record number
1377040
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