Title of article
Carbonylative formation of N-acetyl-2,6-difluorobenzamide through N–H bond activation of 2,6-difluorobenzamide with Ni(II) complex supported with phosphine ligands
Author/Authors
Chenggen Wang، نويسنده , , Hongjian Sun، نويسنده , , Qingping Hu، نويسنده , , Xiaoyan Li، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2011
Pages
5
From page
2815
To page
2819
Abstract
Fluorinated imide, N-acetyl-2,6-difluorobenzamide (C6H3F2-2,6)C(O)NHC(O)Me 2, could be obtained through one-pot reaction of NiMe2(PMe3)3 with 2,6-difluorobenzamide (C6H3F2-2,6)C(O)NH21 in CO atmosphere. A postulated reaction mechanism via N–H bond cleavage and carbonylative reductive elimination on nickel center was partly experimentally confirmed. An important intermediate (C6H3F2-2,6)C(O)HNNiMe(PMe3)23 was isolated and structurally characterized.
Keywords
Carbonylation , Organic fluoride , Imide , nickel , Trimethylphosphine
Journal title
Journal of Organometallic Chemistry
Serial Year
2011
Journal title
Journal of Organometallic Chemistry
Record number
1377330
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