Title of article
Carboxy-functionalized dithiolate di-iron complexes related to the active site of Fe-only hydrogenase
Author/Authors
Vijendran Vijaikanth، نويسنده , , Jean-François Capon، نويسنده , , Frédéric Gloaguen، نويسنده , , François Y. Pétillon، نويسنده , , Philippe Schollhammer، نويسنده , , Jean Talarmin، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2007
Pages
5
From page
4177
To page
4181
Abstract
Reactions of the di-iron complex [Fe2(μ-S)2(CO)6]2− with carboxy-functionalized dihalide derivatives (XCH2)2R (X = Cl, R = NC6H4CH2CO2CH3; X = Br, R = C6H3COOH, C6H3COON(COCH2)2) gave new functionalized dithiolate di-iron complexes [Fe2(μ-SRS)(CO)6] (R = (CH2)2NC6H4CH2CO2CH3 (1), (CH2)2C6H3COOH (2), (CH2)2C6H3COON(COCH2)2 (3)) in low yields. The azadithiolate complex 1 has been characterized by a single crystal X-ray diffraction analysis and studied by electrochemical methods.
Keywords
Hydrogenase , Di-iron complex , Carboxy-functionalized dithiolate , Electrochemistry , Molecular structure
Journal title
Journal of Organometallic Chemistry
Serial Year
2007
Journal title
Journal of Organometallic Chemistry
Record number
1377970
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