Title of article
The combination of mononuclear metallocene and phenoxyimine complexes to give trinuclear catalysts for the polymerization of ethylene
Author/Authors
Christian G?rl، نويسنده , , Helmut G. Alt، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2007
Pages
27
From page
5727
To page
5753
Abstract
Trinuclear complexes were synthesized by combination of metallocene and phenoxyimine zirconium complexes. After activation with methylalumoxane (MAO), these catalysts polymerize ethylene with moderate and good activities. Due to the presence of different catalytic centers, polyethylenes with broad or bimodal molecular weight distributions were obtained.
Keywords
Metallocene complexes , Bis(phenoxyimine)zirconium complexes , Salicylaldehydes , ethylene polymerization , Bimodal molecular weight distribution , Multinuclear complexes
Journal title
Journal of Organometallic Chemistry
Serial Year
2007
Journal title
Journal of Organometallic Chemistry
Record number
1378242
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