Title of article
Dimethylmalonyltrialkylphosphoranes: probing the steric effect on phosphorus and its stereochemical consequence in esterification reactions of chiral secondary alcohols
Author/Authors
J. Dyck، نويسنده , , S. Zavorine، نويسنده , , A.J. Robertson، نويسنده , , A. Capretta، نويسنده , , V. Larichev، نويسنده , , J. Britten، نويسنده , , J. McNulty، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
5
From page
2548
To page
2552
Abstract
High chemical yields and high levels of stereochemical inversion are demonstrated in the phosphorane-mediated esterification reaction of chiral alcohols with non-hindered carboxylic acids through the incorporation of sterically non-hindered alkyl groups of phosphorus.
Keywords
Trialkylphosphoranes , Esterification , Stereocontrol
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1378467
Link To Document