Title of article
1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, image: Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour
Author/Authors
F. Geoffrey، نويسنده , , F. Geoffrey N. Cloke، نويسنده , , Peter B. Hitchcock، نويسنده , , John F. Nixon، نويسنده , , D. James Wilson، نويسنده , , L?szl? Nyul?szi، نويسنده , , Tam?s K?rp?ti، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
7
From page
3983
To page
3989
Abstract
The 1-triphenylstannyl-2, 4, 5-tritertiarybutyl-1,3-diphosphole, View the MathML sourcePh3SnP2C3Bu3t, which has been synthesised from Ph3SnCl and View the MathML sourceKP2C3Bu3t, has been fully structurally characterised in the solid state but in solution undergoes ready intra-molecular shifts of the Ph3Sn-group around the 1,3-diphospholyl ring. Theoretical calculations concerning both the structure and the dynamic process are presented and discussed.
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1378653
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