Title of article
Preparation and properties of palladium(II) complexes of 3-oxo-1-(2,4,6-tri-t-butylphenyl)-1,3-diphosphapropenes
Author/Authors
Katsunori Nishide، نويسنده , , Hongze Liang، نويسنده , , Shigekazu Ito، نويسنده , , Masaaki Yoshifuji، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
7
From page
4809
To page
4815
Abstract
Kinetically stabilized 3-oxo-1,3-diphosphapropenes were prepared by oxidation of 1,3-diphosphapropenes with m-CPBA or from reaction of the corresponding phosphaethenyllithium with phosphinic chloride. The 3-oxo-1,3-diphosphapropenes were used as P,O-unsymmetrical bidentate ligands and the catalytic activity of the palladium(II) complexes in some cross-coupling reactions was investigated.
Keywords
Phosphorus ligand , Phosphaalkene , palladium complex , X-ray crystallography , cross-coupling reaction
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1378749
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