Title of article
Rhodium–NHC-complexes as potent catalysts in the hydroformylation of 1-octene
Author/Authors
Martin Bortenschlager، نويسنده , , Jan Schütz، نويسنده , , Denise von Preysing، نويسنده , , Oskar Nuyken، نويسنده , , Wolfgang A. Herrmann، نويسنده , , Ralf Weberskirch، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
5
From page
6233
To page
6237
Abstract
We present an overview of eight different rhodium-N-heterocyclic carbene (NHC) complexes 1–8 and their catalytic activity and selectivity in hydroformylation of 1-octene. It could be shown that activity can be increased by going from electron-rich NHC- to electron-poor NHC-ligands. However, no increase in the selectivity could be achieved by introducing bulky substituents to the NHCs.
Keywords
Steric/electronic effects , NHC/rhodium catalysts , hydroformylation
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1379029
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