Title of article
Transformation of an η1-coordinated phosphaalkyne into a bridging phosphinidene ligand
Author/Authors
Christopher D. Andrews، نويسنده , , Andrew D. Burrows، نويسنده , , Michael Green، نويسنده , , Jason M. Lynam، نويسنده , , Mary F. Mahon، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
4
From page
2859
To page
2862
Abstract
The tripalladium cluster [Pd3(μ3-CO)(μ-dppm)3](PF6)2 (1) reacts with two equivalents of tBuCP to give [Pd3(μ-dppm)3(η1-PCBut)2](PF6)2 (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd3(μ-dppm)3(η1:μ3-PCH2But)(OCMe2)](PF6)2 (3). Compound 3 has been characterized by X-ray crystallography.
Keywords
phosphaalkynes , Palladium , Phosphinidene ligands , Clusters
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379402
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