Title of article
Gold–ruthenium compounds containing bridging phosphide or thiolate groups: Crystal structures of the intermediate species [Ru3(CO)8L(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCtriple bond; length of mdashCSiMe3})] (L = NMe3 or PPh2H)
Author/Authors
Esther Delgado، نويسنده , , Elisa Hern?ndez، نويسنده , , Miguel A. Maestro، نويسنده , , Angel Nievas، نويسنده , , Maria Villa، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
6
From page
3596
To page
3601
Abstract
New tetranuclear complexes have been prepared using bridging phosphide or thiolate groups between phosphine gold fragments and the compound [Ru3(CO)9(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCtriple bond; length of mdashCSiMe3})]. The crystal structures of the intermediates [Ru3(CO)8(NMe3)(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCtriple bond; length of mdashCSiMe3})] and [Ru3(CO)8(PPh2H)(μ3-η2,η4,η3-{Me3SiCC(C2Fc)SC(Fc)CSCtriple bond; length of mdashCSiMe3})] have been solved.
Keywords
Triruthenium complexes , Gold–ruthenium compounds , Ruthenium carbonyls
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379497
Link To Document