Title of article
Derivatives of 1,1′-bis(diphenylphosphino)ferrocene (dppf): Electrochemistry, complexation and the X-ray structures of 1,1′-bis(diphenylphosphino)osmocene (dppo) and [PdCl2(dppo)]
Author/Authors
Sarah L. Martinak، نويسنده , , Lauren A. Sites، نويسنده , , Sarah J. Kolb، نويسنده , , Katherine M. Bocage، نويسنده , , William R. McNamara، نويسنده , , Arnold L. Rheingold، نويسنده , , James A. Golen، نويسنده , , Chip Nataro، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
6
From page
3627
To page
3632
Abstract
The oxidative electrochemistry of 1,1′-bis(diphenylphosphino)osmocene (dppo) and 1,1′-bis(diphenylarsino)ferrocene (dpaf) was studied in dichloromethane with tetrabutylammonium hexafluorophosphate as the supporting electrolyte. The [MCl2(P∩P)] (M = Pd or Pt; P∩P = dppo or 1,1′-bis(diphenylphosphinoindenyl)iron) complexes were prepared, studied electrochemically and the X-ray structures of dppo and [PdCl2(dppo)] were determined.
Keywords
1 , 1?-Bis(diphenylphosphino)osmocene , 1 , 1?-Bis(diphenylphosphinoindenyl)iron , crystal structures , 1 , Electrochemistry , Cyclic voltammetry , 1?-Bis(diphenylarsino)ferrocene
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379501
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