Title of article
The first metallacarborane triple-decker complexes with a bridging borole ligand
Author/Authors
Dmitry A. Loginov، نويسنده , , Dmitry V. Muratov، نويسنده , , Zoya A. Starikova، نويسنده , , Pavel V. Petrovskii، نويسنده , , Alexander R. Kudinov، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
6
From page
3646
To page
3651
Abstract
The (borole)iodide complex [(η5-C4H4BPh)RhI]4 reacts with the carborane anion [Carb′]− (Carb′ = 9-SMe2-7,8-C2B9H10) giving (Carb′)Rh(η5-C4H4BPh) (2). Reactions of 2 with dicationic fragments [LM]2+ afford the μ-borole triple-decker complexes [(Carb′)Rh(μ-η5:η5-C4H4BPh)ML]2+ [LM = Cp∗Ir (4), (Carb′)Rh (7)] or the arene-type complexes [(Carb′)Rh(μ-η5:η6-C4H4BPh)ML]2+ [LM = Cp∗Rh (3), (Carb′)Ir (8)]. The structure of 4(BF4)2 was determined by X-ray diffraction.
Keywords
Boron , boron heterocycles , Metallacarboranes , Iridium , Rhodium , Triple-decker complexes
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379504
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