Visible-light-induced photocatalytic activity of TiO2−xNy prepared by solvothermal process in urea–alcohol system

Nitrogen-doped anatase, rutile and brookite titania photocatalyst TiO2−xNy which can be excited by visible light were prepared by mixing aqueous TiCl3 solutions with urea ((NH2)2CO) and various type of alcohols followed by solvothermal treatment at 190 °C. The phase composition, crystallinity, microstructure and specific surface area of titania powders greatly changed depending on the pH and type of solvents. Violet, yellowish and grayish TiO2−xNy with excellent visible light absorption and photocatalytic activity were prepared. The TiO2−xNy powders prepared in urea–methanol solution showed excellent photocatalytic ability for the oxidative destruction of nitrogen monoxide under irradiation of visible light λ > 510 nm.