Study of fuel insolubles: Formation conditions and characterization of copper compounds

The solids formed in the systems containing copper in different oxidation states, in the presence and absence of hexanoic acid and dodecanethiol, together and separately, at room temperature, were studied. The experiments were performed in a mineral oil matrix, free of sulfur compounds and metals; a diesel oil matrix; and the reagents alone, without any matrix. The deposits formed were analyzed by elemental analysis (EA), infrared spectroscopy (IR), thermogravimetric analysis (TGA) and total copper by inductively coupled plasma-optical emission spectrometry (ICP-OES), for their identification and determination of the probable structures. In samples containing both hexanoic acid and dodecanethiol, when there is copper(I), anhydrous copper(II) hexanoate is preferentially formed, but in samples of copper(II), copper(II) mercaptate is formed first. In samples of metallic copper in mineral oil matrix, no deposit formations occur. In all cases in which deposits were formed, they were the same as in diesel oil matrix.