Application of capillary gas chromatography to studies on solvation thermodynamics

The potentiality of capillary gas chromatography (GC) as a means for research on solubility phenomena is focused. Basic thermodynamic information can be obtained in a simple and direct way from this technique relying on few parameters with their associated errors tightly controlled. An unexplored field of solvation phenomenology inaccessible to other techniques is revealed by the accuracy of capillary GC, provided that relevant chromatographic variables are utilized and an adequate treatment of the experimental information performed. The present article reviews different approaches for the attainment of basic thermodynamic information through capillary GC. Some traditional concepts on the treatment of chromatographic data for physicochemical measurement are questioned. Applications of the technique to research on solubility phenomena are depicted.