Title of article
Synthesis, reactivity and crystal structure of perfluoroalkylated diethoxyphosphinyl triphenylphosphorane
Author/Authors
Jiang، نويسنده , , Guo-Fang and Sun، نويسنده , , Jie and Shen، نويسنده , , Yanchang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
4
From page
207
To page
210
Abstract
Synthesis and reactivity of perfluoroalkylated diethoxyphosphinyl triphenylphosphoranes is described. The crystal structure of [(1-diethoxyphosphinyl)-(2-dimethylmethylidene)-3,3,4,4,4-pentafluorobutylidene] triphenylphosphorane has been determined and the bond P-(ylide) order is 1.84 which accounts for its lower reactivity with benzaldehyde than diethoxyphosphinylmethylidene triphenylphosphorane.
Keywords
Diethoxyphosphinyl triphenylphosphoranes , Perfluoroalkylated compounds , 4 , 4 , 4-pentafluorobutylidene] triphenylphosphorane , 3
Journal title
Journal of Fluorine Chemistry
Serial Year
2001
Journal title
Journal of Fluorine Chemistry
Record number
1603135
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