• Title of article

    Trifluoromethylation of carbon and boron with CF3SiMe3/NMe4F: formation of NMe4[trans-CF3CFCFB(CF3)3]

  • Author/Authors

    Hübinger، نويسنده , , Regina and Pawelke، نويسنده , , Gottfried، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    115
  • To page
    118
  • Abstract
    Trimethylamine-trifluoroethenyl-bis(trifluoromethyl)borane [F2CCF(CF3)2B·NMe3] (1) reacts with NMe4[(CF3)2SiMe3] in THF solution to form trimethylamine-bis(trifluoromethyl)pentafluoropropenylborane [trans-CF3CFCF(CF3)2B·NMe3] (3), the fluoroborate NMe4[trans-CF3CFCF(CF3)2BF] (4), the novel borates NMe4[trans-CF3CFCFB(CF3)3] (5) and NMe4[cyclo-(CF3)2BCF2CFCF2CF3] (6).
  • Keywords
    NMR data , fluorine , boron , Silicon , Small ring
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2002
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1603559

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1603559