Title of article
Access to the structures of fluoromagnesium compounds: synthesis and structural characterization of the β-diketiminato magnesium fluoride [{CH(CMeNAr)2}Mg(μ-F)(THF)]2·toluene
Author/Authors
Hao، نويسنده , , Haijun and Roesky، نويسنده , , Herbert W. and Ding، نويسنده , , Yuqiang and Cui، نويسنده , , Chunming and Schormann، نويسنده , , Mark and Schmidt، نويسنده , , Hans-Georg and Noltemeyer، نويسنده , , Mathias and ?emva، نويسنده , , Boris، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
5
From page
143
To page
147
Abstract
β-Diketiminato magnesium fluoride [{CH(CMeNAr)2}Mg(μ-F)(THF)]2·toluene (Ar=2,6-i-Pr2C6H3, 2·toluene) was synthesized. The molecular structure of 2 revealed for the first time, the double fluoro bridge feature between the two magnesium atoms with a typical MgF bond length (average 1.95 Å).
Keywords
Magnesium , ?-Diketiminato ligands , Bischelating ligands , fluorides
Journal title
Journal of Fluorine Chemistry
Serial Year
2002
Journal title
Journal of Fluorine Chemistry
Record number
1603570
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