Title of article
Trifluoro analog of Hagemann’s ester: access to angularly CF3-substituted heterobicyclic compounds
Author/Authors
Julien and Barhoumi-Slimi، نويسنده , , Thouraya and Crousse، نويسنده , , Beno??t and Ourévitch، نويسنده , , Michèle and El Gaied، نويسنده , , Moncef and Bégué، نويسنده , , Jean-Pierre and Bonnet-Delpon، نويسنده , , Danièle، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
5
From page
137
To page
141
Abstract
The selective reduction of the trifluoro analog of the Hagemann’s ester 1 provided corresponding cyclohexenols, which underwent a Johnson–Claisen rearrangement leading to diesters 3. These latter are precursors of tetrahydroisochromanes 5 and octahydroisoquinoline 7a bearing an angular trifluoromethyl substituent.
Keywords
Hagemann’s ester , Heterocycles , Trifluoromethyl compounds , Johnson–Claisen rearrangement
Journal title
Journal of Fluorine Chemistry
Serial Year
2002
Journal title
Journal of Fluorine Chemistry
Record number
1603649
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