• Title of article

    Addition of cyclic ethers and acetals to ethyl 3,3-difluoro-2-methylpropenoate

  • Author/Authors

    Bumgardner، نويسنده , , Carl L. and Burgess، نويسنده , , Jason P.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    345
  • To page
    348
  • Abstract
    Ethyl 3,3-difluoro-2-methylpropenoate forms 1 : 1 adducts with tetrahydrofuran and 1,3-dioxolanes under free radical conditions. In contrast no 1 : 1 adducts are observed when tetrahydropyran and 1,3-dioxanes are used as sources of α-alkoxy radicals. An explanation is presented based on FMO and radical stability arguments.
  • Keywords
    acetals , Ethyl , Cyclic ethers
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1603705