Title of article
A novel synthetic approach to fluorine-containing acetylenic compounds based on Nicholas reaction
Author/Authors
Konno، نويسنده , , Tsutomu and Nagai، نويسنده , , Go and Ishihara، نويسنده , , Takashi، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
9
From page
510
To page
518
Abstract
The fluorine-containing dicobalthexacarbonyl complex, prepared readily from γ-fluoroalkylated propargyl acetates and Co2(CO)8, reacted smoothly with various nucleophiles at the propargylic position, followed by oxidative decomplexation under the influence of Fe(NO3)3, to afford fluoroalkylated alkynes bearing various types of alkyl side chains in good to high yields.
Keywords
Propargyl acetates , Dicobaltoctacarbonyl , Nicholas reaction , Fluorine-containing alkynes
Journal title
Journal of Fluorine Chemistry
Serial Year
2006
Journal title
Journal of Fluorine Chemistry
Record number
1603795
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