Title of article
Functionalized fluorinated arylethers by ring-opening of 1,2,3,4-tetrafluorodibenz[b,f][1,4]oxazepine
Author/Authors
Doherty، نويسنده , , Brenda and Nieuwenhuyzen، نويسنده , , Mark H. Saunders، نويسنده , , Graham C. and Sloan، نويسنده , , M.Shane، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
5
From page
15
To page
19
Abstract
Treatment of 1,2,3,4-tetrafluorodibenz[b,f][1,4]oxazepine with acetyl or benzoyl chloride produces the fluorinated aryl ethers bearing amide and aldehyde functionalities, RCONHC6H4-2-OC6F4CHO-2 (2a R=Ph; 2b R=Me). The structures of intermediate compounds produced by addition of acid chloride across the imine bond and by partial hydrolyis of the resulting chlorine-containing compound have been determined.
Keywords
Dibenzoxazepine , ring-opening , Arylethers , crystal structure
Journal title
Journal of Fluorine Chemistry
Serial Year
2003
Journal title
Journal of Fluorine Chemistry
Record number
1607318
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