• Title of article

    New perfluorovinylethers through the bis(fluoroxy)difluoromethane (BDM) chemistry

  • Author/Authors

    Navarrini، نويسنده , , Walter and Corti، نويسنده , , Sandra، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    9
  • From page
    189
  • To page
    197
  • Abstract
    In the present work we give an overview of the CF2(OF)2 radical reactivity and report the synthesis of new perfluorovinylethers. CF2CFOCF2OCF2CF3 and CF2CFOCF2OCF2CF2OCF3 are prepared in a semi-continuous methodology starting from CF2(OF)2. These highly reactive vinylethers are characterized by the OCF2O group directly bonded to the insaturation. For this reason they are excellent candidates for the preparation of very low Tg perfluororubbers.
  • Keywords
    Synthesis , Hypofluorites , Bis(fluoroxy)difluoromethane , Perfluororubbers , Perfluorovinylethers
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2004
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1607993

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1607993