• Title of article

    Pentafluoro-λ6-sulfanyl (SF5) perfluoroalkyl iodides-synthesis and reaction with ethylene and tetrafluoroethylene: Crystal structure of SF5(CF2)4CH2CH2I

  • Author/Authors

    Nixon، نويسنده , , Paul G. and Mohtasham، نويسنده , , Javid and Winter، نويسنده , , Rolf and Gard، نويسنده , , Gary L. and Twamley، نويسنده , , Brendan and Shreeve، نويسنده , , Jean’ne.M.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    8
  • From page
    553
  • To page
    560
  • Abstract
    A series of reactions between SF5CF2CF2I and SF5(CF2)4I with F2CCF2 was carried out in an effort to find the most effective methods for chain-extension. Also, for the first time, SF5(CF2)8I and SF5(CF2)10I have been prepared and isolated. The reaction conditions for the addition of H2CCH2 were also investigated. A determination of the crystal structure of the SF5(CF2)4CH2CH2I has been carried out: the crystal system is monoclinic, with space group P2(1)/n and a=23.465(5) Å; b=6.0971(12) Å; c=44.892(9) Å; α=90°; β=99.38(3)°; γ=90°; Z=20.
  • Keywords
    SF5-perfluoroalkyl iodides and ethylene derivatives , crystal structure , SF6 derivatives
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2004
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1608128

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1608128