Title of article
Methyl 3,3,3-trifluoropyruvate hemiaminals: Stability and transaminations
Author/Authors
Dolensk?، نويسنده , , Bohumil and Kv??ala، نويسنده , , Jaroslav and Paleta، نويسنده , , Old?ich، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
7
From page
745
To page
751
Abstract
Hemiaminals of methyl 3,3,3-trifluoropyruvate with aromatic amines, benzylic monoamines and diamines were prepared and their interconversions studied using NMR spectrometry. In solution, benzylic hemiaminals were found to be stable in contrast to aromatic hemiaminals, which, in turn, were stable in the solid state.
Keywords
Methyl 3 , Methyl 3 , 3-trifluoropyruvate , 3 , 3 , 3-trifluoro-2-oxopropanoate , Hemiaminal equilibrium , Trifluoromethyl synthon
Journal title
Journal of Fluorine Chemistry
Serial Year
2005
Journal title
Journal of Fluorine Chemistry
Record number
1608933
Link To Document