Title of article
One-electron oxidation of alkyl alkoxybenzenes by ω-fluorosulfonylperfluorodiacyl peroxide
Author/Authors
Dong، نويسنده , , Jun-Hua and Dou، نويسنده , , Hongyan and Zhao، نويسنده , , Cheng-Xue، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
8
From page
205
To page
212
Abstract
The oxidation of p-methylanisole 3a, dialkoxybenzenes 3b, 3c and alkyl dialkoxybenzenes 3d–h by perfluorodi[1-(2-fluorosulfonyl) ethoxy]propionyl peroxide 1 afforded main products 4-ω-fluorosulfonylperfluoroalkyl-4-alkoxy-2,5-cyclohexa-dienones and minor ring ω-fluorosulfonylperfluoroalkylation products. The electron transfer mechanism of the reactions is also proved by ESR detection of the radical cations of the donor molecules.
Keywords
Alkyl alkoxybenzene , one-electron oxidation , ESR , Electron transfer , ?-Fluorosulfonylperfluorodiacyl peroxide
Journal title
Journal of Fluorine Chemistry
Serial Year
2006
Journal title
Journal of Fluorine Chemistry
Record number
1609162
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