• Title of article

    Rearrangement and fluorination of quinidinone in superacid

  • Author/Authors

    Vincent Chagnault، نويسنده , , Vincent and Thibaudeau، نويسنده , , Sébastien and Jouannetaud، نويسنده , , Marie-Paule and Jacquesy، نويسنده , , Jean-Claude and Cousson، نويسنده , , Alain and Bachmann، نويسنده , , Christian، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2007
  • Pages
    5
  • From page
    55
  • To page
    59
  • Abstract
    In HF/SbF5 at −78 °C, quinidinone 1 yields fluoroketone 3 (50% yield). The reaction implies a cyclic carboxonium ion as an intermediate, which reacts through a concerted rearrangement and fluorination to yield ketone 3.
  • Keywords
    Superacids , Rearrangement , Cinchona alkaloids , Carboxonium ion , fluorination
  • Journal title
    Journal of Fluorine Chemistry
  • Serial Year
    2007
  • Journal title
    Journal of Fluorine Chemistry
  • Record number

    1609530