Title of article
A new method for the synthesis of trifluoromethylating agents—Diaryltrifluoromethylsulfonium salts
Author/Authors
Yagupolskii، نويسنده , , Lev M. and Matsnev، نويسنده , , Andrej V. and Orlova، نويسنده , , Raisa K. and Deryabkin، نويسنده , , Boris G. and Yagupolskii، نويسنده , , Yurii L.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
6
From page
131
To page
136
Abstract
A new synthetic method has been developed to prepare diaryltrifluoromethylsulfonium salts from diaryldifluorosulfuranes by the action of Me3SiCF3/F−. This reaction is the transformation of nucleophilic trifluoro-methylating reagent into electrophilic one.
Keywords
Diaryltrifluoromethylsulphonium salts , Diarylsulfides , Nucleophilic mechanism , Trifluoromethyl group
Journal title
Journal of Fluorine Chemistry
Serial Year
2008
Journal title
Journal of Fluorine Chemistry
Record number
1610012
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