Title of article
Solubility of trifluoroethoxyphthalocyanines and -subphthalocyanines in liquid and supercritical carbon dioxide
Author/Authors
Das، نويسنده , , Banibrata and Tokunaga، نويسنده , , Etsuko and Shibata، نويسنده , , Norio and Kobayashi، نويسنده , , Nagao، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
3
From page
652
To page
654
Abstract
In an analysis of the solubility of a wide range of phthalocyanines (Pcs) and its analogues (SubPcs) in liquid and/or supercritical CO2, compounds with trifluoroethoxy substituents were found to exhibit high solubility. To our knowledge, this is the first example of Pc compounds soluble in 100% CO2. This unprecedented unique property of trifluoroethoxy substituted Pcs might have particular applications in catalysis in organic reactions as well as dyes for solar cells by CO2 delivering coatings.
Keywords
Phthalocyanine , solubility , Carbon dioxide , Subphthalocyanine
Journal title
Journal of Fluorine Chemistry
Serial Year
2010
Journal title
Journal of Fluorine Chemistry
Record number
1610925
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