Title of article
Trialkyl borate assisted amination of fluorinated 1,3-diketones for synthesis of N,N′-1,2-phenylen-bis(β-aminoenones) and their Ni(II), Cu(II) and Pd(II) complexes
Author/Authors
Chizhov، نويسنده , , Dmitrii L. and Pervova، نويسنده , , Marina G. and Samorukova، نويسنده , , Mariya A. and Khmara، نويسنده , , Ekaterina F. and Filyakova، نويسنده , , Vera I. and Saloutin، نويسنده , , Viktor I. and Charushin، نويسنده , , Valery N.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
8
From page
394
To page
401
Abstract
An effecient synthetic method for fluorinated tridentate β-aminoenones and tetradentate bis(β-aminoenones) via amination of fluorinated 1,3-diketones with o-phenylenediamine in the presence of trialkyl borates was developed. Ni(II), Cu(II) and Pd(II) complexes with tetradentate bis(β-aminoenones) were obtained. Their gaschromatographic behaviour and main fragmentation paths in the electron ionization mass spectra were described.
Keywords
complexes , Gas-chromatography–mass-spectrometry , amination , Fluorinated ligands
Journal title
Journal of Fluorine Chemistry
Serial Year
2011
Journal title
Journal of Fluorine Chemistry
Record number
1611259
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