Title of article
Henry reaction of fluorinated nitro compounds
Author/Authors
Hu، نويسنده , , Huawei and Huang، نويسنده , , Yangen and Guo، نويسنده , , Yong، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
7
From page
108
To page
114
Abstract
The Henry (nitroaldol) reaction of fluorinated nitro compounds with various aromatic aldehydes and a fluorinated aliphatic aldehyde to give β-fluoro-β-nitroalcohols which bearing a fluorinated quaternary carbon center was reported. The relative configuration of the major diastereoisomer of 2-fluoro-2-nitro-1-(4-nitrophenyl)-3-phenylpropanol (5bf) was determined by X-ray single crystal analysis.
Keywords
Henry reaction , Enantioselectivity , organocatalysis , aldehyde , fluorine
Journal title
Journal of Fluorine Chemistry
Serial Year
2012
Journal title
Journal of Fluorine Chemistry
Record number
1611584
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