Title of article
Hydrodefluorination of polyfluoro-2-naphthylamines by Zn in aqueous NH3: A correlation of the product distribution and the computationally predicted regioselectivity of the substrate radical anion fragmentation
Author/Authors
Selivanova، نويسنده , , Galina A. and Reshetov، نويسنده , , Alexey V. and Beregovaya، نويسنده , , Irina V. and Vasil’eva، نويسنده , , Nadezhda V. and Bagryanskaya، نويسنده , , Irina Yu. and Shteingarts، نويسنده , , Vitalij D. Shteingarts، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
9
From page
64
To page
72
Abstract
Hydrodefluorination of heptafluoro-2-naphthylamine and its less fluorinated analogues by zinc in aqueous ammonia has been explored with respect to the possibility to occur and to rationalize the product distribution in terms of the mechanism including formation and fragmentation of a polyfluoroarene radical anion.
Keywords
Polyfluoro-2-naphthylamines , Hydrodefluorination , quantum-chemical calculations , X-ray analysis , CVA measurements
Journal title
Journal of Fluorine Chemistry
Serial Year
2012
Journal title
Journal of Fluorine Chemistry
Record number
1611788
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